Dy2O3对钛酸锶钡基陶瓷结构及介电性能的影响
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江苏省高校自然科学基金资助项目(11KJB430007)

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Effects of Dy2O3 on the Structure and Dielectric Properties of Barium Strontium Titanate Based Ceramics
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    摘要:

    采用传统固相法制备Dy2O3掺杂(Ba0.7Sr0.3)TiO3系电容器介质陶瓷,通过扫描电镜、X线衍射仪及LCR测试系统,研究不同含量的Dy2O3对体系微观结构及介电性能的影响。结果表明,随着Dy2O3添加量的增大,(Ba0.7Sr0.3)TiO3陶瓷平均粒径减小且Dy2O3 掺杂(Ba0.7Sr0.3)TiO3陶瓷均为钙钛矿结构单相固溶体。Dy2O3通过占据钙钛矿晶格A、B位引起(Ba0.7Sr0.3)TiO3陶瓷晶格畸变,体系自发极化能力降低,进而显著降低了体系室温相对介电常数及介电损耗。随着Dy2O3添加量的增大,(Ba0.7Sr0.3)TiO3陶瓷居里温度向负温方向移动,且体系的相对介电常数及介电损耗随温度变化显著。

    Abstract:

    The Dy2O3 doped (Ba0.7Sr0.3)TiO3 ceramics for capacitor applications were prepared by the conventional solid state method. The effects of different content of Dy2O3 on the microstructure and dielectric properties of (Ba0.7Sr0.3)TiO3 were investigated by the scanning electron microscope, X ray diffractometer and LCR measure system. It has been found that the average grain size of (Ba0.7Sr0.3)TiO3 ceramics decreases with the increase of Dy2O3 addition content and Dy2O3 doped (Ba0.7Sr0.3)TiO3 ceramics are single phase solid solution with perovskite structure. Dy2O3 can significantly reduce the relative dielectric constant and dielectric loss by occupying the A site orB site in perovskite structure, causing the unit cell distortion and thus resulting in the weakening of spontaneous polarization. With the increase of Dy2O3 addition content, the Curie temperature of (Ba0.7Sr0.3)TiO3 ceramics shifts to lower temperautre range. The relative dielectric constant and dielectric loss of Dy2O3 doped (Ba0.7Sr0.3) TiO3 system are significantly influenced by temperature.

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张晨,肖佳楠,徐新进. Dy2O3对钛酸锶钡基陶瓷结构及介电性能的影响[J].压电与声光,2012,34(6):898-901. ZHANG Chen, XIAO Jianan, XU Xinjin. Effects of Dy2O3 on the Structure and Dielectric Properties of Barium Strontium Titanate Based Ceramics[J]. PIEZOELECTRICS AND ACOUSTOOPTICS

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  • 在线发布日期: 2012-11-23
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