Nd2O3掺杂(Sr0.9Ba0.1)La4Ti4O15陶瓷的结构及微波性能
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陕西省科学技术研究发展计划基金资助项目(2014K08-10);航空科学基金资助项目(20140853013)

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Microstructure and Microwave Properties of Nd2O3-doped(Sr0.9Ba0.1)La4Ti4O15Ceramics
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    摘要:

    采用传统的固相反应法制备(Sr0.9Ba0.1)La4Ti4O15+x%Nd2O3(质量分数0≤x≤8,BSN)系微波介质陶瓷,并对其物相组成、晶体结构及微波介电性能进行分析。研究结果表明,Nd2O3含量的增加降低了BSN陶瓷的烧结温度,陶瓷的主晶相为SrLa4Ti4O15相,并伴随有少量第二相La2TiO5的生成。在微波频率下,随着Nd2O3含量的增加,BSN陶瓷的介电常数及谐振频率温度系数变化小,品质因数与频率之积(Q×f)值提高,优化出掺杂4%Nd2O3的(Sr0.9Ba0.1)La4Ti4O15陶瓷具有最佳微波介电性能:εr=43.2,Q×f=42 015 GHz(6.024 GHz),τf=-9.6 μ℃-1。

    Abstract:

    (Sr0.9Ba0.1)La4Ti4O15+xwt%Nd2O3(0≤x≤8,BSN) ceramics were prepared by the conventional solid state processing method, the microstructure and microwave dielectric properties of BSN ceramics were investigated. The results show that adding Nd2O3 into BSN ceramics would lower the sintering temperature, a few of La2TiO5 phase was also observed in the ceramics besides SrLa4Ti4O15. With increasing the content of Nd2O3, the dielectric constant and the temperature coefficient of resonance frequency changed little, but the value of Q×fincreases obviously. (Sr0.9Ba0.1)La4Ti4O15+4%Nd2O3 ceramic shows the optimal dielectric properties of εr=43.2, Q×f=42 015 GHz(6.024 GHz),τf=-9.6 μ℃-1.

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王利 高峰 张大帅 王敏 秦梦婕. Nd2O3掺杂(Sr0.9Ba0.1)La4Ti4O15陶瓷的结构及微波性能[J].压电与声光,2016,38(6):892-896. WANG Li GAO Feng ZHANG Dashuai WANG Ming QIN Mengjie. Microstructure and Microwave Properties of Nd2O3-doped(Sr0.9Ba0.1)La4Ti4O15Ceramics[J]. PIEZOELECTRICS AND ACOUSTOOPTICS

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  • 在线发布日期: 2016-12-20
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