Abstract:MgNb2O6-doped (Ba0.71Sr0.29 )TiO3 ((Ba,Sr)TiO3 )-based capacitor ceramics were prepared by solid state method. The influence of MgNb2O6 (MNO) doping amount on the dielectric properties, phase composition, and microstructure of (Ba,Sr)TiO3-based ceramics were investigated by X-ray diffraction (XRD) and scanning elec tronic microscopy (SEM), among other tests. The results showed that the relativity permittivity of (Ba,Sr)TiO3 based capacitor ceramics decreased; dielectric loss increased, then decreased, and finally increased; the resistivity first decreased, then increased, and finally decreased; and withstand voltage strength (Eb ) first decreased firstly, then increased, and finally decreased when MNO doping amount increased. When the doping amount of MNO was 2.0 wt%, the (Ba,Sr)TiO3 ceramics had a maximum dielectric constant of 1 670 and minimum dielectric loss of 0.005 6. When the doping amount of MNO was 8.0 wt%, (Ba,Sr)TiO3 ceramics had a maximum resistivity of 65.23×1010 Ω·cm and maximum withstand voltage strength of 7.7 kV/mm (DC). When the doping amount of MNO was 10.0 wt%, (Ba,Sr)TiO3 ceramics exhibited less percentage of capacitance variation with temperatures of +0.18% and -28.29%. (Ba,Sr)TiO3 ceramics doped with MNO had a perovskite structure. The doping of MNO can decrease capacitance variation with temperature.